Wednesday, May 16, 2012

Blog 11.1 Table J and the Activity Series of Metals [Due Wed May 23rd]

Blog Questions:
1.      The solutions you used were all nitrate solutions. For example, the silver ion solution (Ag1+) is really a solution of silver nitrate (AgNO3). The complete REDOX equation for the reaction between magnesium metal and silver solution is as follows:
         
              Mg(s)    +    AgNO3(aq)     -->    Mg(NO3)2(aq)   +    Ag(s)



a) The nitrate ion is known as a “spectator ion”.  Explain why you think this name is appropriate:

b) In the reaction between magnesium and silver solution, what is oxidized

What is reduced?  


2. Propose a rule that predicts whether or not metal X and metal ion Y+2 will react, based on Table J.

3.  Answer the two “lab questions” from page 1 of this lab:
1.    What is an “ACTIVity series” and how does it relate to what I already know about the behavior of metallic and non-metallic elements?
2.   How is an activity series used to predict (or explain) which metal (or non-metal) is more reACTIVE than another?

4. History of Metals
Currently there are 86 known metals. Before the 19th century only 24 of these metals had been discovered and, of these 24 metals, 12 were discovered in the 18th century. Therefore, from the discovery of the first metals, gold and copper, until the end of the 17th century, some 7700 years, and only 12 metals were known. Four of these metals, arsenic, antimony, zinc and bismuth, were discovered in the thirteenth and fourteenth centuries, while platinum was discovered in the 16th century. The other seven metals, known as the “Metals of Antiquity,” were the metals upon which civilization was based. The first 4 had been discovered and were in use before cultures had developed the ability to communicate in writing.  They are referred to in the oldest written documents we can find (like the book of Genesis in the Bible, as well as ancient Egyptian, Phoenician and Babylonian texts).  These seven metals were:
1.     Gold, 6,000 BC
2.     Copper, 4,200 BC
3.     Silver, 4,000 BC
4.     Lead, 3,500 BC
5.     Tin, 1,750 BC
6.     Iron, 1,500 BC
7.     Mercury, 750 BC

On Table J, the elements above H2 are prone to oxidation in the air, and are therefore unlikely to be found in pure form on the Earth’s surface.  Rather, they are in compounds called “ores” which are metal oxides, like Fe2O3 (iron ore).  Why do you think gold, silver and copper were discovered so long ago by humans, but the other 4 metals were discovered later?

 
A significant advance in human civilization occurred when humans discovered how to extract copper from copper ore.  When mixed with tin, the alloy is called bronze and is harder than either metal separately.  Go to this website.  Check out two things:
·         How copper was “smelted” in ancient times.
·         How bronze was made.

 
Enrichment:
Ag1+ is a very important ion in the history of Rochester, since it was the primary ingredient in George Eastman’s black and white KODAK film industry.  Research how this ion is used in photography.

Monday, May 7, 2012

Blog 10.1 Solubility and Curves

10.2 Section

1. Which samples are definitely polar?  How do you know?
2. Which samples are definitely non-polar?  How do you know?
 
3. From the data, what can you conclude about the polarity of ethanol?
 
4. Would you expect ethanol to dissolve in water?   How about in hexane?
 
5. Classify the following as non-polar or polar molecules.  Then, predict their solubility in each solvent.

Type of Molecule
Solubility in Water
Solubility in Hexane
NH3




I2




HCl





6.  Why do ionic materials dissolve so well in water, but not in hexane?

Enrichment: Atmospheric gases such as oxygen, nitrogen and carbon dioxide are capable of dissolving in water. Make a prediction regarding how much you expect these gases to dissolve based on their polarity. See if you can find or think of at least one reason why oxygen and carbon dioxide need to be able to dissolve in water for aquatic life to flourish.


10.2 Section 

What things made a significant difference in how quickly the KClO3 dissolved. If you wanted to get something to dissolve quickly, what things can you do in order to make it happen. The more important question is: Why does this happen at the particle level, what does particle collisions and attractions have to do with this? Does surface area relate to this at all, and if it does what can you do to change that variable to make it happen quicker.

Describe how the terms unsaturated, saturated, and super saturated apply to the experiment. At what point was the solution saturated, and at what point was it unsaturated. I will tell you now that with potassium chlorate in this experiment, you never formed a supersaturated solution, it precipitated out before that happened.

ENRICHMENT: Find out how rock candy is made. I am sure you can find a recipe very easily, but I want you to apply this to chemistry using the vocabulary we have learned. This is a little more difficult task than just finding the recipe. If you want make it, try it, it is delicious.